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71 1 Unique functional materials might be created based on the cyclobutadienecobalt-containing polymers because of their chemical and thermal stability and of the peculiar square geometry of the cyclobutadiene ligands. Re ecting on the squarer geometry of the cyclobutadiene moieties, thermotropic liquid-crystalline polymers can be designed by the polycondensation of the regioisomerically pure organocobalt monomers.9 12 As shown in scheme 3, the Ni(0)-promoted dehalogenation polycondensation of both 1,2- and 1,3- regioisomerically pure bifunctional ( 5-cyclopentadienyl)( 4-cylobutadiene)cobalt complexes (6A and 6B) yields zigzag and rigid-rod -conjugated polyarylenes (7A and 7B), respectively.11 Both of these polymers exhibit thermotropic and, in some cases, lyotropic liquid-crystalline behavior. However the properties of these two series of the polymers are entirely di erent; the zigzag-type polymers (7A) exhibit thermotropic liquid crystals in a lower temperature range and higher solubility in organic solvents compared to the rigid-rod Laying the Foundation
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