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Because of the importance of the product oligomers for the production of detergents, plasticizers, comonomers, and specialty chemicals, oligomerization of simple olefins still attracts considerable attention. s03 The most active catalysts in ethylene oligomerization are Ni-based systems with monoanionic bidentate [p,O]S04,SOS and [N,O]S06 ligands, which work at high temperature and pressure (80-120 C and 70-140 atm). It was also found that neutral [P,O] ligands affording cationic Ni complexes oligomerize ethylene under much milder reaction conditions so7 and similar cationic Pd complexes codimerize ethylene with styrene. S08 More recently, various other neutral chelating [N,N]s09-S11 and [p,N]S12 ligands afforded the synthesis of highly active Ni- and Pd-based oligomerization catalysts. Highly active bis(pyridyl)ironS13 ,s14 and cobaltS14 ethylene oligomerization catalysts have been reported. NOTE
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3.41 The Edit Picture sheet lets you take a video snapshot of yourself or choose a photo either from a folder or directly from iPhoto or Photo Booth.
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