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lms exposed on both the greenhouse and racks. Figure 5.3 presents change in percent elongation at break versus exposure time for lms exposed in racks and greenhouse lms. Both the lms have shown a downward trend, but a faster drop in measured property is observed for lm exposed on operating greenhouse. The higher rate of degradation on lm exposed on greenhouses is attributed to the higher temperatures, humidity, and wind stresses, conditions that prevailed in an enclosed greenhouse tunnel [38, 40]. Furthermore, the higher degradation of greenhouse-exposed lms may also be due to sulfur and halogen-based chemicals, which have adverse effects on HALS-stabilized LDPE lms.
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You can also use the DesignCenter to insert raster images, as described in 26.
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Object snaps are essential for 3D work. Turn on OSNAP and set running object snaps. Object snaps ensure that you re specifying the point that you want. However, don t forget that in 3D drawings, you can have two lines, one on top of the other. Use a view that enables you to see the two lines separately so that you can pick the object snap that you want. The Apparent Intersection object snap is especially useful for 3D work. You can use it to specify points that look as if they intersect from your viewpoint, even though in true 3D they would not intersect.
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For comparison Mars distance from the sun (maximum) is 154,700,000 miles; Jupiter s distance from the sun (maximum) is 507,000,000 miles.
2
Alcohol (which contains 7 kcal/g) should be restricted to healthy drinking limits (21 units/week for men, 14 units/week in women) or lower. As well as providing excess energy, alcohol can be hazardous in patients taking insulin or sulphonylureas, because it blocks the acute increase in hepatic glucose production that enables recovery from hypoglycaemia. Diabetic sweets and foods containing sorbitol (a cause of diarrhoea) or arti cial sweeteners are expensive and best avoided.
in this chapter
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7: Functions
which de nes the p-type orbital is not shown), is indicated by an arrow in Figure 3.23. It is along a line that makes an angle somewhat greater than 90 with the CO bond. Attachment of a Lewis base means addition of electrons to the pCO orbital and is accompanied by loss of the p bond (if both bonding and antibonding orbitals are equally occupied, there is no bond). WHY DOES IT WORK AND WHEN MIGHT IT NOT The application of orbital interaction theory to understand the electronic structures of molecules, as illustrated in the case of the carbonyl group in Figure 3.21 above, is one of two conceptually distinct applications. Characteristics of the bonding and structure of the molecule were deduced from interactions of the group orbitals situated as they would be in the `` nished'' molecule. This application is in the regime of strong interactions and short distances, the regime in which the foundations of orbital interaction theory, oneelectron theory as exempli ed by Hartree Fock theory, have a rm footing and a demonstrated record of successes. Since the electrons are con ned to a small region of space, lack of speci c account of electron correlation is not serious in that its inclusion would not substantially a ect the one-electron description, or the error incurred may be assumed to be reasonably constant when comparing di erent conformations. The second broad area of application of orbital interaction theory is in the area of intermolecular interactions, from which many aspects of chemical reactivity may be inferred. This application, as exempli ed in Figures 3.22 and 3.23, is in the realm of weaker interactions and larger distances, conditions suitable to application of perturbation theories. The dominant orbital interactions in this regime are of the two-electron, two-orbital type, and usually, a single orbital interaction between the HOMO of one molecule and the LUMO of the other is su cient for the purpose. Unfortunately, the one-electron theoretical foundation for this kind of long-range interaction involving electron transfer is much less sound. Accurate descriptions of weak interactions usually require theoretical procedures which go beyond Hartree Fock theory for the reason that some account must be taken of the correlation of the electron motions, particularly within the same orbital. The reason for this is easy to understand and is illustrated in Figure 3.24. Prior to interaction (Figure 3.24a), the electrons are localized to the HOMO of the donor, B. At intermediate separations (Figure 3.24b), where the orbitals of A and B overlap, the space available to the electrons is greatly increased and the electrons are able to separate. After bond formation (Figure 3.24c), the space available to the electrons is again restricted. In the intermediate stage (Figure 3.24b), the lack of electron correlation inherent in one-electron theories is most strongly felt. In terms of valence bond structures, MO theory places comparable emphasis on the three structures R1 , R2 , and R3 , whereas, in reality, resonance structure R2 alone most accurately represents the true situation. Resonance structure R2 corresponds to a con guration in which a single electron has been transferred from B to A. The reactivity of B as a donor (nucleophile) is expected to be correlated with its ionization potential [76]. Likewise, the reactivity of A as a Lewis acid should be correlated with the electron a nity of A. Post-Hartree Fock theoretical analyses of heterolytic bond breaking [77] and the reverse, cation anion combination reactions [78], have elucidated the role of the missing electron correlation. In the valence bond con guration mixing (VBCM) treatment of Shaik [9, 78], the valence bond con gurations of reacting species are regarded as ``surfaces'' whose avoided crossing de nes the barrier to the reaction. The Hartree Fock model is expected to work well
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You don t necessarily need to download a file to edit it. See the previous Editing a file directly on the Web server section for more information.
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