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At suitably high temperatures, hydrazine and H2X decomposition products will leave the sample in a gaseous form, although the H2X product can further decompose to H2 and X (increasing probability across the series S, Se, Te). For X = S or Se, the decomposition process is complete by approximately 350 C (Fig. 3.4), highlighting the low-temperature nature of this process.33 Note the signi cantly lower decomposition temperature (<200 C) for X = S, primarily because of the more volatile nature of sulfur relative to selenium. For low-temperature deposition of metal chalcogenides using a precursor that consists of metal chalcogenide anions and hydrazinium cations, sul des will generally facilitate lower processing temperatures compared with selenides
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