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Note the new visual enhancement added to the Disk Management screen in Vista. Underneath the drive name is a colored bar; each color has a meaning: White: The drive contains no data, no files. Blue: The drive contains files. Red: The drive has less than 15 percent of its maximum capacity available. Dropping under the 15 percent threshold is enough to warrant a red (warning) color because it brings with it four important consequences: First and foremost, you might be running out of disk space. If this is the drive where the Windows installation is located, your machine might slow down when booting up or during normal usage because some of the available space in this drive is also used as a temporary memory cache for your PC. If you have less than 15 percent disk space available in the drive (as well as a minimum of 300MB) where your Windows installation is located, you might not be able to run System Restore, which allows you to retrieve files, programs, and other data in the event that your computer is damaged. (For more on System Restore, see 11.) When you have less than 15 percent disk space available in a drive, you cannot run Disk Defragmenter. Thus, you cannot create any new partitions from this area of your hard drive.
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distance.80 Because of the important role of Coulomb interactions, the lowtemperature conductance in nanocrystal solids often follows the ln G T 1/2 law known as Efros Scklovskii variable range hopping.79 Hydrazine treatment does not cause changes of nanocrystal shape and size, but it reduces the interparticle spacing from 1.1 nm to 0.3 nm.68,76 Hydrazine is a Br nsted base and can gently remove the capping ligands by reacting with oleic acid adsorbed on the surface of as-synthesized nanocrystals. Replacement of bulky oleic acid with small hydrazine molecules reduces the interparticle spacing, thereby increasing the exchange coupling energy. The bidentate hydrazine molecules can also link PbSe nanocrystals.70 Moreover, hydrazine is a strong Lewis base, which enables it to saturate dangling bonds at the nanocrystal surface by donating a lone pair of electrons.32 Finally, replacement of oleic acid ( 2) with hydrazine ( 52) also substantially reduce the charging energy Ec. The increase of and the decrease of Ec helps to close the Hubbard gap, thus enabling the insulator metal Mott transition in the nanocrystal solid.80 Finally, hydrazine behaves as a charge-transfer n-type dopant.81 Colloidal synthesis allows for controlling not only the size but also the shape of semiconductor nanocrystals. The anisotropic shape of the nanocrystals can provide certain advantages for their use as the building blocks for electronic and optoelectronic devices. Sun and Sirringhaus observed about an order-of-magnitude improvement of carrier mobility in the lms assembled from 65 nm by 10-nm ZnO nanorods (Fig. 10.13a) compared with the lms of spherical ZnO nanoparticles.82,83 The morphology of nanorod lms strongly depends on the processing conditions. Colloidal solutions of rod-like nanoparticles can form lyotropic liquid-crystalline phases with nematic and smectic ordering of individual nanorods.84,85 In the nematic phase, the nanorods are unidirectional aligned, enabling an easy path for charge carriers along the nanorods (Fig. 10.13b). The ability to control orientation of the nanorods and to achieve large domains of aligned nanorod lms allows signi cant improvement of the transport properties. Field-effect transistors with mobilities of up to 1.2 1.4 cm2 V 1 s 1 and the on/off ratio of 105 106 were demonstrated in spin-coated, in-plane, aligned ZnO nanorod lms.83 Colloidal nanocrystals can be used for inexpensive and high-throughput solution fabrication of both n- and p-channel eld-effect devices by stamping or ink-jet printing. The eld-effect mobilities in PbSe and ZnO nanocrystal FETs are comparable with or better than mobilities in pentacene and other solution-processed organic lms.77 The ease of switching between n- and p-transport in PbSe nanocrystal arrays can enable CMOS FET circuits and p n junctions for solar cells. Recent observation of carrier multiplication (i.e., generation of several excitons per one absorbed photon) in PbS, PbSe, and PbTe nanocrystals86 makes these materials promising for thin- lm photovoltaics. Sargent et al. recently demonstrated ultrasensitive solution-cast infrared photodetectors using PbS nanocrystal solids.87 The
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